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ePSXe crashes on exit
This is if you have Office 2007/2010 installed. You need to modify the installation and remove Microsoft Sharepoint Workspace, reboot, then RENAME this file:
C:\Program Files (X86)\Microsoft Office\Office14\GROOVEEX.dll

Reboot again, this will allow you to finally delete the file that is causing the crash on exit.
Try this out.
 
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