Ah, never mind, I pressed triangle on the character, and its there, I went straight to the ability screen instead, been years since I played this last, maybe you're not supposed to learn it from there ~_~
Oh, I can't seem to change the control config of the start button in ePSXe 1.6.0 to anything, everytime I press anything, it changes the square button to whatever I press it to, and the Start button rermains to be V, any solutions?
No, you can't use pad plugins with ePSXe windows version, neither alone nor with any frontend. If you want to assign enter to a button, you'll either have to find an external app to configure it (wich exists, but whose name i can't recall), or edit the registry with regedit (HKEY_CURRENT_USER\Software\epsxe\config\Keys1 stores your current control's configuration). You need to know the scancodes to do that, check them here.