Perhaps I can explain.
The problem currently is that the ISO driver is unable to virtualize redbook audio.
Under normal circumstances, when the PSX (and thus the PSX emulator), calls for a CD audio track, it leaves it to the player to start playing a track just like you would any audio CD player.
You can hear CD Audio from CDs if you have some means of routing the sound from the drive to the computer. Most often that means a 4-pin analog sound connection to your sound card, but most modern drives can also send out the data digitally (via a 2-pin connection) for crisper sound. The trick is you need a sound card capable of receiving that data.
Back to ISOs. The ISO driver is currently unable to interpret a "play track" command. There are two reasons for this.
First is that the ISO driver currently doesn't look for the CUE. The BIN file is only half of the equation: it's just the raw data. The CUE tells burners what is what, and the ISO driver will need that file to tell just what part of the BIN is an audio track.
Second is that the ISO driver currently lacks a CD Audio virtualizer. Once the driver is capable of interpreting CUEs, it must also be able to read the sound data, convert it to some playabale format, and then route the PCM data on to the sound card. Such a virtualizer will require some work because of its independent nature, but in general, those are the two reasons ISOs don't play redbook.