In short: If you use Peops, then it will boot the CD/DVD in you drive (and it will not ask you what you want to play, of course)
If you use linuzaps plugin or any other image plugin, then it will ask you what game you want to run (unless you specifically said in the plugin what game to start without asking you).
You also might want to try File->Run Elf and sellect the elf file (eg: slus_1456.24, sles_3267.25) as some games don`t boot normally with run cd (saying they are illegal copies).
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